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For example, a ketone and its enol form are keto-enol tautomers

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However, excessive extracellular Mn 2+ can disrupt intracellular Ca 2+ signaling in astrocytes by competitively occupying Ca 2+ -binding sites, thus interfering with mitochondrial Ca 2+ homeostasis ( 3+ causes astrocyte swelling via oxidative/nitrosative pathways (Rama Rao et al., 2007)

Under normal conditions, antioxidants neutralize these molecules before damage occurs