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This movement combined with the change in charge introduced by the mutations modifies the binding cavity, forcing glutathione to adopt a nonproductive binding mode and permitting trypanothione and to a certain degree also the weak substrate glutathionylspermidine to assume a productive mode

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10.3390/ijms242216353 380 WangM.TangG.ZhouC.GuoH.HuZ.HuQ.et al

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