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Tryptophan can be converted to indole-3-pyruvate (I3P) by interleukin-4-induced-1 (IL4i1), which protects cancer cells from ferroptosis through scavenging lipophilic radicals, increasing the GSH/ Glutathione disulfide (GSSG) ratio, upregulating the expression of SLC7A11 and targeting some genes in the antioxidant signaling pathway, such as hemeoxygenase-1 (HO-1) [87]

BMJ 313, 14171418

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Because if not, if it dissociates to any extent, it seems it could then be absorbed, and, at least according to Cutler, this could provoke redistribution as the ALA is not being given according to its half life