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While iron is stored safely in ferritin in the injured spinal cord, it can, however, be released by NCOA4-mediated shuttling of ferritin to autophagosomes for degradation (ferritinophagy)

Implication of the proprotein convertases in iron homeostasis: proprotein convertase 7 sheds human transferrin receptor 1 and furin activates hepcidin

More importantly, in the absence of His, Pro was found to play a very important role in Cu binding and the role of other amino acids (threonine, Gln, glycine, and methionine were negligible in presence of His and Pro (Irtelli et al., 2009)

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Leukemia 10(10):1563-9, 1996